Synthesis and structure of novel coordination compounds based on [Re6Q8(CN)6]4- Q = S, Se) and (SnMe3)+

被引：8
|
作者：
Tarasenko, M. S. [1 ]
Ledneva, A. Yu. [1 ]
Kurat'eva, N. V. [1 ]
Naumov, D. Yu. [1 ]
Kim, Sung-Jin [2 ]
Fedorov, V. E. [1 ]
Naumov, N. G. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
[2] Ewha Womans Univ, Dept Chem, Seoul, South Korea
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 33卷 / 12期
关键词：
D O I：
10.1134/S1070328407120020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of SnMe3Cl with salts of the cluster anionic complexes [Re(6)Q(8)(CN)(6)](4-) (Q = S, Se), gave novel complexes [{(SnMe3)(2)(OH)}(2){SnMe3}(2){Re6S8(CN)(6)}] (I), (Me4N)(2)[{SnMe3(H2O)}(2){Re6Se8(CN)(6)} (II), [{(SnMe2)(4)(mu(3)-O)(2){Re6Se8(CN)(6)} (III), and [(SnMe2)(4)(mu(3)-O)(2)(mu(2)-OH)(2)(H2O)(2)]{SnMe3}(2){Re6Se8(CN)(6)}(IV). The structures of I-IV were determined by X-ray diffraction. Compounds I, IV have the chain structures with the CN-SnMe3-NC bridges between the cluster anions [Re(6)Q(8)(CN)(6)](4-). Compound II contains isolated fragments {SnMe3(H2O)}(2){Re6Se8(CN)(6)}(2-). In the polymer framework of compound III, the cluster anionic complexes [Re6Se8(CN)(6)](4-) are bound by the complex cations [(SnMe2)(4)(mu(3)-O)(2)](4+) formed due to the hydrolysis of the initial SnMe3Cl.
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收藏
页码：876 / 885
页数：10
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