Ring-opening metathesis polymerization of norbornene and dicyclopentadiene catalyzed by Cp2TiCl2/RMgX

被引：11
|
作者：
Zhang, DF
Huang, JL
Qian, YL
Chan, ASC
机构：
[1] E China Univ Chem Technol, Organomet Chem Lab, Shanghai 200237, Peoples R China
[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 133卷 / 1-2期
关键词：
ring-opening metathesis polymerization; norbornene; dicyclopentadiene;
D O I：
10.1016/S1381-1169(98)00087-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ring-opening metathesis polymerization (ROMP) of norbornene (NBE) and dicyclopentadiene (DCPD) catalyzed by Cp2TiCl2 (Cp = eta(5)-cyclopentadienyl) and a series of different RMgX (R = CH3, C2H5, i-C3H7, n-C4H9, n-C6H13, C6H5, X = Cl Pr, I) were studied. The catalytic system Cp2TiCl2/CH3MgI is the most active for the ROMP of NBE and DCPD, but Cp2TiCl2 with other Grignards appeared rather low catalytic activity. The mechanism of polymerization with Cp2TiCl2 and different Grignard agents was discussed. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：131 / 133
页数：3
相关论文
共 50 条
  • [21] Ring-opening metathesis polymerization of norbornene in supercritical carbon dioxide.
    Hu, XC
    Blanda, MT
    Venumbaka, SR
    Cassidy, PE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U304 - U304
  • [22] Advances in the study on ring-opening metathesis polymerization of norbornene and its derivatives
    Zhang, Danfeng
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2000, 16 (01): : 13 - 15
  • [23] Online monitoring of ring-opening metathesis polymerization of cyclooctadiene and a functionalized norbornene
    Alb, Alina M.
    Enohnyaket, Pascal
    Craymer, Jeanette F.
    Eren, Tarik
    Coughlin, E. Bryan
    Reed, Wayne F.
    MACROMOLECULES, 2007, 40 (03) : 444 - 451
  • [24] THE RING-OPENING METATHESIS POLYMERIZATION OF NORBORNENE IN SUPERCRITICAL CARBON-DIOXIDE
    MISTELE, CD
    DESIMONE, JM
    THORP, HH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 126 - POLY
  • [25] Ring-opening metathesis polymerization of norbornene-benzoladderene (macro)monomers
    Scannelli, Samantha J.
    Alaboalirat, Mohammed
    Troya, Diego
    Matson, John B.
    POLYMER CHEMISTRY, 2023, 14 (41) : 4726 - 4735
  • [26] THE MECHANISM OF STEREOSELECTIVE RING-OPENING METATHESIS POLYMERIZATION OF NORBORNENE AND SEVERAL DERIVATIVES
    GILLAN, EMD
    HAMILTON, JG
    MACKEY, OND
    ROONEY, JJ
    JOURNAL OF MOLECULAR CATALYSIS, 1988, 46 (1-3): : 359 - 371
  • [27] [CP2TiCl2] catalyzed polymerization in water:: polymerization of methylmethacrylate to a high molecular weight polymer
    Bhattacharjee, M
    Patra, BN
    POLYMER, 2004, 45 (10) : 3111 - 3114
  • [28] Functional Hyperbranched Polymers Using Ring-Opening Metathesis Polymerization of Dicyclopentadiene with Monoterpenes
    Mathers, Robert T.
    Damodaran, Krishnan
    Rendos, Matthew G.
    Lavrich, Michael S.
    MACROMOLECULES, 2009, 42 (05) : 1512 - 1518
  • [29] Two commercially available initiators for the retarded ring-opening metathesis polymerization of dicyclopentadiene
    Leitgeb, Anita
    Wappel, Julia
    Urbina-Blanco, Cesar A.
    Strasser, Simone
    Wappl, Christina
    Cazin, Catherine S. J.
    Slugovc, Christian
    MONATSHEFTE FUR CHEMIE, 2014, 145 (09): : 1513 - 1517
  • [30] Two commercially available initiators for the retarded ring-opening metathesis polymerization of dicyclopentadiene
    Anita Leitgeb
    Julia Wappel
    César A. Urbina-Blanco
    Simone Strasser
    Christina Wappl
    Catherine S. J. Cazin
    Christian Slugovc
    Monatshefte für Chemie - Chemical Monthly, 2014, 145 : 1513 - 1517
12345