On the surface steps of a heterogeneous catalytic reaction

被引：2
|
作者：
Matyshak, V. A. [1 ]
机构：
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
来源：
KINETICS AND CATALYSIS | 2007年 / 48卷 / 06期
关键词：
D O I：
10.1134/S0023158407060080
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Based on a study of the properties of intermediate complexes in the reactions of low-temperature ammonia oxidation and nitrogen oxide reduction in the presence and absence of oxygen on various catalysts, it was hypothesized that the sequence of steps in the formation of reaction products on chemically different catalysts can be the same if the initial adsorption forms of reactants are identical. In this case, variations in catalysts or reaction conditions affect the ratio between reaction rates.
引用
收藏
页码：812 / 817
页数：6
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