Kinetics of the photoreduction of bis(2,4-pentanedionato)copper(II) in chloroform

被引：10

作者：

Ng, W ^{[1
]}

Hoggard, PE ^{[1
]}

机构：

[1] Santa Clara Univ, Dept Chem, Santa Clara, CA 95053 USA

来源：

INORGANICA CHIMICA ACTA | 2001年 / 321卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

bis(2,4-pentanedionato)copper(II); acetylacetonato complexes; photoreduction; chloroform; solvent-initiated;

D O I：

10.1016/S0020-1693(01)00502-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under 254 nm irradiation in chloroform, bis(2,4-pentanedionato)copper(II) is converted to CuCl.2HCl. from which CuCl precipitates at concentrations of 10(-3) M or higher. The photoreaction appears to be completely solvent-initiated, that is, the rate depends on the fraction of light absorbed by the solvent. Both . CCl3 radicals and HCl, produced photolytically, are able to initiate the reaction. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：1 / 4

页数：4

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