Photochemistry and absolute stereochemistry of unique chiral olefins, trans- and cis-1,1′,2,2′,3,3′,4,4′-octahydro-3,3′-dimethyl-4,4′-biphenanthrylidene

被引：15

作者：

Koumura, N ^{[1
]}

Harada, N ^{[1
]}

机构：

[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 11期

关键词：

D O I：

10.1246/cl.1998.1151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photochemistry of unique chiral olefins, (3R,3'R)-(P,P)-(E)-(-)-1,1',2,2',3,3',4,4'-octahydro-3,3'-dimethyl-4,4'-biphenanthrylidene 3 and its isomers (3R,3'R)-(P,P)-(Z)-(+)-4 and (3R,3'R)-(M,M)-(E)-(+)-5, was studied and the absolute stereostructure of (+)-5 was determined by X-ray crystallographic and chemical correlation studies.

引用

页码：1151 / 1152

页数：2

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