Facile Synthesis of Porous Ag Crystals as SERS Sensor for Detection of Five Methamphetamine Analogs

被引:10
|
作者
Qin, Yazhou [1 ]
Mo, Fan [1 ]
Yao, Sen [1 ]
Wu, Yuanzhao [1 ]
He, Yingsheng [2 ]
Yao, Weixuan [1 ]
机构
[1] Zhejiang Police Coll, Key Lab Drug Prevent & Control Technol Zhejiang P, 555 Binwen Rd, Hangzhou 310053, Peoples R China
[2] Natl Antidrug Lab Zhejiang Reg Ctr, Key Lab Drug Control & Monitoring, 555 Binwen Rd, Hangzhou 310053, Peoples R China
来源
MOLECULES | 2022年 / 27卷 / 12期
关键词
Ag crystal; methamphetamine; SERS; porous structure; ENHANCED RAMAN-SCATTERING; GOLD; DENSITY; OXIDE; SIZE; NANOCRYSTALS; EVOLUTION; OCTAHEDRA; ACID;
D O I
10.3390/molecules27123939
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Porous noble metal nanomaterials have attracted extensive attention due to their high specific surface area and surface plasmon resonance effect. However, it is difficult to form porous structures due to the high mobility and low reduction potential of noble metal precursors. In this article, we developed a facile method for preparing porous Ag with a controllable structure at room temperature. Two kinds of Ag crystals with different porous structures were successfully prepared by using AgCl cubes as sacrificial templates. Through the galvanic replacement reaction of Zn and AgCl, Ag crystals with a sponge-like porous structure were successfully prepared. Additionally, using NaBH4 as the reducing agent, we prepared granular porous Ag cubes by optimizing the amount of reducing agent. Both the sponge-like and granular porous Ag cubes have clean and accessible surfaces. In addition, we used the prepared two porous Ag cubes as substrate materials for SERS detection of five kinds of methamphetamine analogs. The experimental results show that the enhancement effect of granular porous Ag is better than that of sponge-like porous Ag. Furthermore, we probed the hot spot distribution of granular porous Ag by Raman mapping. By using granular porous Ag as the substrate material, we have achieved trace detection of 5 kinds of methamphetamine analogs including Ephedrine, Amphetamine, N-Methyl-1-(benzofuran-5-yl)propan-2-amine (5-MAPB), N-Methyl-1-(4-methoxyphenyl)propan-2-amine (PMMA) and N-Methyl-1-(4-fluorophenyl)propan-2-amine (4-FMA). Furthermore, to achieve qualitative differentiation of analogs with similar structures we performed density functional theoretical (DFT) calculations on the Raman spectra of the above analogs. The DFT calculations provided the vibrational frequencies, Raman activities, and normal mode assignment for each analog, enabling the qualitative differentiation of the above analogs.
引用
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页数:12
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