Crystal structure of [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)]

被引：0

作者：

Al-Jahdali, M

Baker, PK ^{[1
]}

Drew, MGB

机构：

[1] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2000年 / 30卷 / 03期

关键词：

tungsten(II); diiodo; dicarbonyl; triisopropylphosphite; 3-hexyne; crystal structure;

D O I：

10.1023/A:1009531014474

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

[WI2(Co)(2){P((OPr)-Pr-i)(3)}(eta (2)-EtC2Et)] crystallizes in the monoclinic space group P2(1)/n, with a = 11.101(12), b = 16.272(18), c = 14.892(17) Angstrom, beta = 93.27(1), Z = 4. The geometry can be considered to be pseudo-octahedral, with the 3-hexyne ligand occupying one site, with two iodo-groups, and the P((OPr)-Pr-i)(3) ligand completing the equational plane of ligands, with two trans-carbonyl groups occupying the axial sites.

引用

页码：181 / 184

页数：4

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