Crystal structure of [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)]

被引：0

作者：

Al-Jahdali, M

Baker, PK ^{[1
]}

Drew, MGB

机构：

[1] Univ Wales, Dept Chem, Bangor LL57 2UW, Gwynedd, Wales

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2000年 / 30卷 / 03期

关键词：

tungsten(II); diiodo; dicarbonyl; triisopropylphosphite; 3-hexyne; crystal structure;

D O I：

10.1023/A:1009531014474

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

[WI2(Co)(2){P((OPr)-Pr-i)(3)}(eta (2)-EtC2Et)] crystallizes in the monoclinic space group P2(1)/n, with a = 11.101(12), b = 16.272(18), c = 14.892(17) Angstrom, beta = 93.27(1), Z = 4. The geometry can be considered to be pseudo-octahedral, with the 3-hexyne ligand occupying one site, with two iodo-groups, and the P((OPr)-Pr-i)(3) ligand completing the equational plane of ligands, with two trans-carbonyl groups occupying the axial sites.

引用

页码：181 / 184

页数：4

共 50 条

[1] Crystal structure of [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)]
Mutlaq Al-Jahdali
Paul K. Baker
Michael G.B. Drew
Journal of Chemical Crystallography, 2000, 30 : 181 - 184
[2] 3-hexyne complexes of molybdenum(II) and tungsten(II).: Crystal structures of [WI2(CO)(PPh3)2(η2-EtC2Et)] and [WI2(CO){Ph2P(CH2)3PPh2}(η2-EtC2Et)]
Al-Jahdali, M
Baker, PK
Drew, MGB
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (02): : 171 - 178
[3] Crystal structure of [WI2(CO)3{P(OMe)3}2]
Paul K. Baker
Michael B. Hursthouse
Latifah A. Latif
K.M. Abdul Malik
Journal of Chemical Crystallography, 1998, 28 : 639 - 643
[4] Crystal structure of [WI2(CO)3{P(OMe)3}2]
Baker, PK
Hursthouse, MB
Latif, LA
Malik, KMA
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1998, 28 (08) : 639 - 643
[5] 3-Hexyne complexes of molybdenum(II) and tungsten(II) containing phosphite ligands:: X-ray crystal structures of [MoI2(CO)(NCMe){P(OPh)3}(η2-EtC2Et], [MoI2(Co)(dppe)(η2-EtC2Et)] and [MI2(CO) {P(OiPr)3}2(η2-EtC2Et)] (M = Mo and W)
Al-Jahdali, M
Baker, PK
Drew, MGB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 622 (1-2) : 228 - 241
[6] Seven-coordinate complexes of molybdenum(II) and tungsten(II) containing phosphite donor ligands:: X-ray crystal structures of [WI2(CO)3{P(OiPr)3}2] and [WI2(CO)2{P(OMe)3}3]
Baker, PK
Coles, SJ
Harrison, NS
Latif, LA
Meehan, MM
Hursthouse, MB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 566 (1-2) : 245 - 250
[7] 3,3-dimethyl-1-butyne complexes of tungsten(II).: Crystal structures of [WI2(CO)(NCPh)(η2-HC2But)2] and [WI2(CO){P(OR)3}2(η2-HC2But)] (R = Me and Et)
Baker, PK
Drew, MGB
Moore, DS
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 658 (1-2) : 77 - 87
[8] Crystal structures of [WI2(CO)3{Ph2P(CH2)nPPh2}] (n = 2 or 3)
Paul K. Baker
Michael G.B. Drew
Steve P. Gonsalves
Archie W. Johans
Margaret M. Meehan
Journal of Chemical Crystallography, 2002, 32 : 113 - 118
[9] Crystal structures of [WI2(CO)3{Ph2P(CH2)nPPh2}] (n=2 or 3)
Baker, PK
Drew, MGB
Gonsalves, SP
Johans, AW
Meehan, MM
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2002, 32 (5-6) : 113 - 118
[10] THE REACTIONS OF [WI2(CO)(NCME)(ETA-2-RC2R)2] (R = ME AND PH) .1. THE SYNTHESIS AND SPECTRAL PROPERTIES OF THE NEW BISPHOSPHITE COMPLEXES [WI2(CO)(P(OME)3)2-(ETA-2-RC2R)], (WI2(CO)(POET)3)2-(ETA-2RC2R)), (WI2(CO)(P(OPR-I)3)2-(ETA-2RC2R)), (WI2(CO)(POBU-N)3)2-(ETA-2RC2R))
BAKER, PK
KEYS, EM
INORGANICA CHIMICA ACTA, 1986, 116 (02) : L49 - L50

← 1 2 3 4 5 →