Synthesis and structural characterization of tetranuclear zinc(II) complexes with a linear array

被引:19
|
作者
Mikuriya, M [1 ]
Ikenoue, S [1 ]
Nukada, R [1 ]
Lim, JW [1 ]
机构
[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan
关键词
D O I
10.1246/bcsj.74.101
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1,3-Bis(salicylideneamino)-2-propanol (H(3)salpro) and 1,3-bis(salicylideneamino)propane (H(2)salpn) react with Zn(ClO4)(2). 6H(2)O and pyrazole (Hpz) to give tetranuclear complexes with a linear Zn-4 array, [Zn-4(Hsalpro)(2)(pz)(2)(Hpz)(2)](ClO4)(2) (1) and [Zn-4(salpn)(2)(pz)(2)(Hpz)(2)] (ClO4)(2) (ClO4)(2) (2), which were characterized by infrared spectra and X-ray crystallography.
引用
收藏
页码:101 / 102
页数:2
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