Robust hydrogen-bonded capsules with stability in competitive media

被引：7
|
作者：
Tiefenbacher, Konrad [2 ,3 ]
Zhang, Kang-da [2 ,3 ]
Ajami, Dariush [2 ,3 ]
Rebek, Julius, Jr. [1 ,2 ,3 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[3] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2015年 / 28卷 / 03期
基金：
美国国家科学基金会;
关键词：
molecular recognition; encapsulation; deep cavitands; host; guest complexes; MOLECULAR CAPSULE; GUEST MOLECULES; DIFFUSION NMR; TETRA UREA; ENCAPSULATION; CALIXARENE; CHLOROFORM; DIMER;
D O I：
10.1002/poc.3378
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The binding behavior of a cavitand introduced by de Mendoza is explored with new guest species. Dimerization to hydrogen-bonded capsules occurs in the presence of appropriate guests, including alkanes, alkylated arenes, stilbenes, benzanilides, and carbodiimides. Peripheral tetraethylene glycol groups are attached to the cavitand to improve solubility. Encapsulation of hydrophobic compounds can be observed in aqueous media. Copyright (c) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码：187 / 190
页数：4
相关论文
共 50 条
  • [41] Hydrogen-bonded polymer capsules formed by layer-by-layer self-assembly
    Ok, S
    Kozlovskaya, V
    Sousa, A
    Libera, M
    Sukhishvili, SA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U531 - U531
  • [42] Tuning pH swelling and permeability of hydrogen-bonded multilayer capsules via polymer hydrophobicity
    Kozlovskaya, Veronika
    Sukhishvili, Svetlana A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
  • [43] 2-COMPONENT SOLITONS AND THEIR STABILITY IN HYDROGEN-BONDED CHAINS
    LAEDKE, EW
    SPATSCHEK, KH
    WILKENS, M
    ZOLOTARIUK, AV
    PHYSICAL REVIEW A, 1985, 32 (02): : 1161 - 1179
  • [44] Encapsulation-Induced Remarkable Stability of a Hydrogen-Bonded Heterocapsule
    Ichihara, Keisuke
    Kawai, Hidetoshi
    Togari, Yuka
    Kikuta, Emi
    Kitagawa, Hitomi
    Tsuzuki, Seiji
    Yoza, Kenji
    Yamanaka, Masamichi
    Kobayashi, Kenji
    CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (11) : 3685 - 3692
  • [45] THE FACTORS AFFECTING THE STABILITY OF HYDROGEN-BONDED POLYPEPTIDE STRUCTURES IN SOLUTION
    SCHELLMAN, JA
    JOURNAL OF PHYSICAL CHEMISTRY, 1959, 62 (12): : 1485 - 1494
  • [46] Structural effects on the stability of some hydrogen-bonded complexes with nucleobases
    Yu, LH
    Schneider, HJ
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 1999, 1999 (07) : 1619 - 1625
  • [47] Postsynthetic Metalation of a Robust Hydrogen-Bonded Organic Framework for Heterogeneous Catalysis
    Han, Bin
    Wang, Hailong
    Wang, Chiming
    Wu, Hui
    Zhou, Wei
    Chen, Banglin
    Jiang, Jianzhuang
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (22) : 8737 - 8740
  • [48] Robust Mesoporous Functional Hydrogen-Bonded Organic Framework for Hypochlorite Detection
    Lin, Zu-Jin
    Qin, Jin-Ying
    Zhan, Xiao-Ping
    Wu, KeChen
    Cao, Gao-Juan
    Chen, Banglin
    ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (18) : 21098 - 21105
  • [49] Effect of competitive solvent on chain dynamics within hydrogen-bonded polyelectrolyte multilayers
    Selin, Victor
    Ankner, John
    Sukhishvili, Svetlana
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [50] Hydrogen-bonded clathrate hydrate as tunable media for efficient methane storage
    Lee, Yunseok
    Moon, Seokyoon
    Seo, Dongju
    Lee, Seungin
    Park, Youngjune
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2022, 10 (05):
12345