Crystallization of Nanometer Ge2Sb2Te5 Amorphous Regions Embedded in the Hexagonal Close Packed Structure

被引:5
|
作者
Mio, A. M. [1 ]
D'Arrigo, G. [2 ]
Carria, E. [1 ,3 ]
Bongiorno, C. [2 ]
Rossini, S. [4 ]
Spinella, C. [2 ]
Grimaldi, M. G. [1 ,3 ]
Rimini, E. [2 ]
机构
[1] Univ Catania, Dipartimento Fis & Astron, I-95123 Catania, Italy
[2] IMM CNR, I-95121 Catania, Italy
[3] MATIS IMM CNR, I-95123 Catania, Italy
[4] Micron Semicond Italia Srl, I-20864 Agrate Brianza, Italy
关键词
FILMS;
D O I
10.1149/2.024204esl
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
As an aid toward a better understanding of data retention of phase change memories we have analyzed in situ by Transmission Electron Microscopy the crystallization of amorphous Ge2Sb2Te5 dots of 100 nm and 20 nm diameter, embedded in the hexagonal crystalline phase. Amorphization was obtained by 40 keV Ge+ irradiation at LN2 through Electron Beam Lithography masked pattern. At 75 degrees C/90 degrees C, crystallization in 100 nm dots occurs by grain growth from the surrounding crystalline material, with an initial growth velocity of 0.6 (6.4) pm/s followed by a slower rate of 0.14 (1.7) pm/s. At 75 degrees C, the 20 nm amorphous regions disappear just after two hours of annealing. (C) 2012 The Electrochemical Society. [DOI:10.1149/2.024204esl] All rights reserved.
引用
收藏
页码:H105 / H107
页数:3
相关论文
共 50 条
  • [31] Crystallization of amorphous Ge2Sb2Te5 films induced by a single femtosecond laser pulse
    Zhang, GJ
    Gu, DH
    Jiang, XW
    Chen, QX
    Gan, FX
    SOLID STATE COMMUNICATIONS, 2005, 133 (04) : 209 - 212
  • [32] The thickness dependence of the crystallization behavior in sandwiched amorphous Ge2Sb2Te5 thin films
    Bai, G.
    Li, R.
    Xu, H. N.
    Xia, Y. D.
    Liu, Z. G.
    Lu, H. M.
    Yin, J.
    PHYSICA B-CONDENSED MATTER, 2011, 406 (23) : 4436 - 4439
  • [33] Crystallization behavior of sputter-deposited amorphous Ge2Sb2Te5 thin films
    Jeong, TH
    Kim, MR
    Seo, H
    Kim, SJ
    Kim, SY
    JOURNAL OF APPLIED PHYSICS, 1999, 86 (02) : 774 - 778
  • [34] Nucleus-driven crystallization of amorphous Ge2Sb2Te5: A density functional study
    Kalikka, J.
    Akola, J.
    Larrucea, J.
    Jones, R. O.
    PHYSICAL REVIEW B, 2012, 86 (14):
  • [35] Nanometer-scale order in amorphous Ge2Sb2Te5 analyzed by fluctuation electron microscopy
    Kwon, Min-Ho
    Lee, Bong-Sub
    Bogle, Stephanie N.
    Nittala, Lakshmi N.
    Bishop, Stephen G.
    Abelson, John R.
    Raoux, Simone
    Cheong, Byung-ki
    Kim, Ki-Bum
    APPLIED PHYSICS LETTERS, 2007, 90 (02)
  • [36] Band Calculation for the Hexagonal and FCC Chalcogenide Ge2Sb2Te5
    Piccinini, Enrico
    Tsafack, Thierry
    Buscemi, Fabrizio
    Brunetti, Rossella
    Rudan, Massimo
    Jacoboni, Carlo
    SISPAD: 2008 INTERNATIONAL CONFERENCE ON SIMULATION OF SEMICONDUCTOR PROCESSES AND DEVICES, 2008, : 229 - +
  • [37] Crystallization of ion amorphized Ge2Sb2Te5 thin films in presence of cubic or hexagonal phase
    De Bastiani, R.
    Carria, E.
    Gibilisco, S.
    Mio, A.
    Bongiorno, C.
    Piccinelli, F.
    Bettinelli, M.
    Pennisi, A. R.
    Grimaldi, M. G.
    Rimini, E.
    JOURNAL OF APPLIED PHYSICS, 2010, 107 (11)
  • [38] Local bonding arrangements in amorphous Ge2Sb2Te5: the importance of Ge and Te bonding
    D. A. Baker
    M. A. Paesler
    G. Lucovsky
    Journal of Materials Science: Materials in Electronics, 2007, 18 : 399 - 403
  • [39] Local bonding arrangements in amorphous Ge2Sb2Te5:: the importance of Ge and Te bonding
    Baker, D. A.
    Paesler, M. A.
    Lucovsky, G.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2007, 18 (Suppl 1) : S399 - S403
  • [40] Amorphous structure melt-quenched from defective Ge2Sb2Te5
    Zhimei Sun
    Journal of Materials Science, 2012, 47 : 7635 - 7641