Enantioselective addition of diethylzinc to aryl aldehydes catalyzed by ADPD imine catalysts

被引：0

作者：

Mino, T ^{[1
]}

Oishi, K ^{[1
]}

Yamashita, M ^{[1
]}

机构：

[1] Doshisha Univ, Fac Engn, Dept Mol Sci & Technol, Kyoto 6100321, Japan

来源：

SYNLETT | 1998年 / 09期

关键词：

(4S,5S)-(+)-5-amino-2,2-dimethyl-4-phenyl-1,3-dioxane; chiral imine; enantioselective addition; diethylzinc; titanium tetraisopropoxide;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of chiral imines 1-4 prepared from (4S,5S)-(+)-5-amino-2, 2-dimethyl-4-phenyl-1,3-dioxane (ADPD) in the enantioselective addition of diethylzinc to aryl aldehydes is reported. Secondary aryl alcohols are obtained up to 85% ee in good yields.

引用

页码：965 / +

页数：3

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