Ruthenium Complexes of 5-MeC2B9-Carborane Ligand: Synthesis and Application in Polymerization Catalysis

被引：6

作者：

Zimina, A. M. ^{[1
]}

Anufriev, S. A. ^{[2
]}

Derendyaeva, M. A. ^{[1
]}

Knyazeva, N. A. ^{[1
]}

Somov, N., V ^{[1
]}

Malysheva, Yu B. ^{[1
]}

Sivaev, I. B. ^{[2
]}

Grishin, I. D. ^{[1
]}

机构：

[1] Lobachevskii State Univ, Nizhnii Novgorod 603950, Russia

[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

DOKLADY CHEMISTRY | 2021年 / 498卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

nido-carborane; ruthenacarboranes; controllable radical polymerization; ATRP; cyclic voltammetry; X-ray diffraction analysis; RADICAL POLYMERIZATION; CHEMISTRY; DESIGN;

D O I：

10.1134/S0012500821060057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New ruthenium complex 3,3-(Ph2P(CH2)(4)PPh2)-3-H-3-Cl-9-Me-closo-3,1,2-RuC2B9H10 (1) and its derivatives 3,3-(Ph2P(CH2)(4)PPh2)-3-Cl-9-Me-closo-3,1,2-RuC2B9H10 (2), 3,3,8-(Ph2P(CH2)(4)PPh-mu-C6H4-o)-3-Cl-9-Me-closo-3,1,2-RuC2B9H9 (3), and 3,3,4,8-(Ph2P(CH2)(4)P-mu-(C6H4-o) 2-3-Cl-9-Me-closo-3,1,2-RuC2B9H8 (4) have been prepared from nido-carborane ligand [5-Me-7,8-C2B9H11](-) containing methyl substituent in the lower belt of basket. The obtained substituted ruthenacarboranes retain geometries and steric configurations of the metal atom typical of unsubstituted analogs, but are characterized by lower values of the Ru(II)-Ru(III) redox potential. The high efficiency of the resulting derivatives as catalysts for controllable methyl methacrylate radical polymerization has been shown.

引用

页码：97 / 103

页数：7

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