Ruthenium Complexes of 5-MeC2B9-Carborane Ligand: Synthesis and Application in Polymerization Catalysis

被引：6
|
作者：
Zimina, A. M. [1 ]
Anufriev, S. A. [2 ]
Derendyaeva, M. A. [1 ]
Knyazeva, N. A. [1 ]
Somov, N., V [1 ]
Malysheva, Yu B. [1 ]
Sivaev, I. B. [2 ]
Grishin, I. D. [1 ]
机构：
[1] Lobachevskii State Univ, Nizhnii Novgorod 603950, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
来源：
DOKLADY CHEMISTRY | 2021年 / 498卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
nido-carborane; ruthenacarboranes; controllable radical polymerization; ATRP; cyclic voltammetry; X-ray diffraction analysis; RADICAL POLYMERIZATION; CHEMISTRY; DESIGN;
D O I：
10.1134/S0012500821060057
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New ruthenium complex 3,3-(Ph2P(CH2)(4)PPh2)-3-H-3-Cl-9-Me-closo-3,1,2-RuC2B9H10 (1) and its derivatives 3,3-(Ph2P(CH2)(4)PPh2)-3-Cl-9-Me-closo-3,1,2-RuC2B9H10 (2), 3,3,8-(Ph2P(CH2)(4)PPh-mu-C6H4-o)-3-Cl-9-Me-closo-3,1,2-RuC2B9H9 (3), and 3,3,4,8-(Ph2P(CH2)(4)P-mu-(C6H4-o) 2-3-Cl-9-Me-closo-3,1,2-RuC2B9H8 (4) have been prepared from nido-carborane ligand [5-Me-7,8-C2B9H11](-) containing methyl substituent in the lower belt of basket. The obtained substituted ruthenacarboranes retain geometries and steric configurations of the metal atom typical of unsubstituted analogs, but are characterized by lower values of the Ru(II)-Ru(III) redox potential. The high efficiency of the resulting derivatives as catalysts for controllable methyl methacrylate radical polymerization has been shown.
引用
收藏
页码：97 / 103
页数：7
相关论文
共 50 条
  • [1] Ruthenium Complexes of 5-MeC2B9-Carborane Ligand: Synthesis and Application in Polymerization Catalysis
    A. M. Zimina
    S. A. Anufriev
    M. A. Derendyaeva
    N. A. Knyazeva
    N. V. Somov
    Yu. B. Malysheva
    I. B. Sivaev
    I. D. Grishin
    Doklady Chemistry, 2021, 498 : 97 - 103
  • [2] New 5-n-C4H9-C2B9-Carborane Ligand and Its Ruthenium Complexes
    A. M. Zimina
    T. V. Kolpakova
    S. A. Anufriev
    E. I. Zueva
    N. V. Somov
    I. B. Sivaev
    I. D. Grishin
    Russian Journal of Coordination Chemistry, 2023, 49 : 329 - 337
  • [3] New 5-n-C4H9-C2B9-Carborane Ligand and Its Ruthenium Complexes
    Zimina, A. M.
    Kolpakova, T. V.
    Anufriev, S. A.
    Zueva, E. I.
    Somov, N. V.
    Sivaev, I. B.
    Grishin, I. D.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (06) : 329 - 337
  • [4] (Arene)ruthenium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]-
    Kudinov, AR
    Perekalin, DS
    Petrovskii, PV
    Grintselev-Knyazev, GV
    RUSSIAN CHEMICAL BULLETIN, 2002, 51 (10) : 1928 - 1930
  • [5] (Arene)ruthenium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]–
    A. R. Kudinov
    D. S. Perekalin
    P. V. Petrovskii
    G. V. Grintselev-Knyazev
    Russian Chemical Bulletin, 2002, 51 : 1928 - 1930
  • [6] Novel carborane complexes of ruthenium with tridentate phosphine ligands: Synthesis and application in Atom Transfer Radical Polymerization
    Kaltenberg, Alexander A.
    Somov, Nikolay, V
    Malysheva, Yulia B.
    Knyazeva, Nadezhda A.
    Piskunov, Alexander, V
    Grishin, Ivan D.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 917
  • [7] Ruthenium carborane complexes: a relationship between the structure, electrochemical properties, and reactivity in catalysis of polymerization processes
    Grishin, I. D.
    Turmina, E. S.
    D'yachihin, D. I.
    Peregudova, S. M.
    Chizhevsky, I. T.
    Grishin, D. F.
    RUSSIAN CHEMICAL BULLETIN, 2013, 62 (03) : 692 - 698
  • [8] Ruthenium carborane complexes: a relationship between the structure, electrochemical properties, and reactivity in catalysis of polymerization processes
    I. D. Grishin
    E. S. Turmina
    D. I. D’yachihin
    S. M. Peregudova
    I. T. Chizhevsky
    D. F. Grishin
    Russian Chemical Bulletin, 2013, 62 : 692 - 698
  • [9] Novel ruthenium(ii) and (iii) carborane complexes with diphosphine ligands and their application in radical polymerization
    Grishin, I. D.
    Knyazeva, N. A.
    Penkal', A. M.
    RUSSIAN CHEMICAL BULLETIN, 2020, 69 (08) : 1520 - 1529
  • [10] Novel ruthenium(ii) and (iii) carborane complexes with diphosphine ligands and their application in radical polymerization
    I. D. Grishin
    N. A. Knyazeva
    A. M. Penkal’
    Russian Chemical Bulletin, 2020, 69 : 1520 - 1529
12345