The synthesis and characterization of new metal-free and metallo phthalocyanines substituted with four dithiatetraoxa macrocyclic moieties

被引：2
|
作者：
Kantekin, Halit [1 ]
Rakap, Murat
Misir, Mirac Nedim
Goek, Halil Zeki
Acar, Irfan
机构：
[1] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 18期
关键词：
isoindolinediimine; nickel(II) phthalocyanine; mixed-donor macrocycle; template effect;
D O I：
10.1080/00958970701217412
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New metal-free phthalocyanine ( 7) fused symmetrically in peripheral positions with four dithiatetraoxa macrocycles, has been synthesized by cyclotetramerization of the isoindoline-diimine derivative of macrocyclic 6. Metallophthalocyanine ( 8) was synthesized by reaction of phthalonitrile derivative ( 5) with anhydrous nickel( II) chloride. The new compounds were characterized by elemental analysis, H-1 and C-13-NMR, IR UV-Vis and mass spectroscopies.
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页码：1965 / 1972
页数：8
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