Template-directed synthesis of donor/acceptor [2]catenanes and [2]rotaxanes

被引:149
|
作者
Griffiths, Kirsten E. [1 ,2 ]
Stoddart, J. Fraser [1 ,2 ]
机构
[1] Univ Calif Los Angeles, California NanoSyst Inst, Los Angeles, CA 90095 USA
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
关键词
2]rotaxanes; 2]catenanes; template-directed synthesis; pseudorotaxanes; donor/acceptor recognition; mechanically interlocked molecules; mechanical bonds; molecular machines; molecular motors; molecular electronics;
D O I
10.1351/pac200880030485
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of mechanically interlocked molecular compounds has advanced by leaps and bounds since the early days of statistical methods and covalent-directing strategies. Template-directed synthesis has emerged as the method of choice for the construction of increasingly complex and functional [2]catenanes and [2]rotaxanes. In particular, mechanically interlocked molecules employing pi-donating and pi-accepting recognition units have been produced with remarkable efficiencies and show great promise in technologies as diverse as molecular electronics and drug delivery.
引用
收藏
页码:485 / 506
页数:22
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