Synthesis, Characterization, and Energetic Properties of 6-Amino-tetrazolo[1,5-b]-1,2,4,5-tetrazine-7-N-oxide: A Nitrogen-Rich Material with High Density

被引：65
|
作者：
Wei, Hao [1 ]
Zhang, Jiaheng [1 ]
Shreeve, Jean'ne M. [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2015年 / 10卷 / 05期
关键词：
perpendicular to energetic materials; nitrogen-rich compounds; N-oxide; tetrazine; tetrazole; DERIVATIVES; PRECURSOR; OXIDES; AZIDE;
D O I：
10.1002/asia.201500086
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and energetic properties of a novel N-oxide high-nitrogen compound, 6-amino-tetrazolo[1,5-b]-1,2,4,5-tetrazine-7-N-oxide, are described. Resulting from the N-oxide and fused rings system, this molecule exhibits high density, excellent detonation properties, and acceptable impact and friction sensitivities, which suggests potential applications as an energetic material. Compared to known high-nitrogen compounds, such as 3,6-diazido-1,2,4,5-tetrazine (DiAT), 2,4,6-tri(azido)-1,3,5-triazine (TAT), and 4,4,6,6-tetra(azido)azo-1,3,5-triazine (TAAT), a marked performance and stability increase is seen. This supports the superior qualities of this new compound and the advantage of design strategy.
引用
收藏
页码：1130 / 1132
页数：3
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