Thermal behavior and flame retardancy of flexible poly(vinyl chloride) treated with zinc hydroxystannate and zinc stannate

被引：30

作者：

Wu, Weihong ^{[2
]}

Qu, Hongqiang ^{[1
]}

Li, Zhi ^{[2
]}

Yuan, Huijie ^{[1
]}

机构：

[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China

[2] Agr Univ Hebei, Coll Sci, Baoding 071001, Peoples R China

来源：

JOURNAL OF VINYL & ADDITIVE TECHNOLOGY | 2008年 / 14卷 / 01期

关键词：

D O I：

10.1002/vnl.20123

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The flame-retardant and smoke-suppressant properties of inorganic tin compounds such as zinc hydroxystannate (ZHS) and zinc stannate (ZS) were studied in comparison with those of alumina trihydrate and magnesium hydroxide through the limiting oxygen index test and a smoke density test. The thermal degradation in air of flexible poly(vinyl chloride) (PVC) treated with the above compounds was studied by thermal analysis from ambient temperature to 800 degrees C. The activation energy was calculated by using the Vyazovkin model-free kinetic method and the Kissinger method. The results showed that tin compounds such as ZHS and ZS could be used as highly effective flame retardants for flexible PVC; these flame retardants enhanced the stability and the activation energy of the oxidation of the char.

引用

页码：10 / 15

页数：6

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