Two luminescent 2D layered copper(I)-olefin coordination polymers with high thermal stability

被引:54
|
作者
Zhang, J
Xiong, RG [1 ]
Chen, XT
Che, CM
Xue, ZL
You, XZ
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
关键词
D O I
10.1021/om001033q
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The solvothermal reactions of 3-pyridylacrylic acid (3-HPYA) and 2-pyridylacrylic acid (2-HPYA) with Cu(CH3CN)(4)BF4 yield two novel highly stable copper(I)-olefin coordination polymers, [(3-PYA)Cu(I)]n (1) and {[(2-PYA)Cu(I)]. (H2O)}n (2), respectively. Both polymers display 2D layered structures and yellow fluorescent emission in the solid state.
引用
收藏
页码:4118 / 4121
页数:4
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