Two novel olefin-copper(I) coordination polymers with DHDAB as building blocks

被引：7
|
作者：
Wang, Guoxi [1 ]
Xing, Zheng [1 ]
Chen, Lizhuang [2 ]
Han, Guangfan [1 ]
机构：
[1] Zhenjiang Coll, Dept Chem Engn, Zhenjiang 212000, Peoples R China
[2] Jiangsu Univ Sci & Technol, Sch Environm & Chem Engn, Zhenjiang 212000, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 783卷
关键词：
Olefin-Cu(I) coordination polymer; Hydrothermal synthesis; Permittivity; COMPLEXES; CHEMISTRY; LIGAND;
D O I：
10.1016/j.jorganchem.2015.01.033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
As stable organometallic moieties, olefin-copper(I) coordination polymers are of interesting properties. In this study, bioactive benzo[d] imidazol derivative 2,20-(1,2-dihydroxyethane-1,2-diyl) bis(1,3-diallyl-3H-benzo[d]imidazol-1-ium) bromide (DHDAB) and CuCl reacted at different temperatures under hydrothermal reaction condition to afford two olefin-Cu(I) coordination polymers with novel structural features, a 3D [(DHDAB)Cu6Br4Cl4](n) frame network and a 1D [(DHDAB)Cu2Cl4](n) infinite chain, respectively. The dielectric constants were measured at different frequencies with temperature variation. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：17 / 21
页数：5
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