The dimeric and two-dimensional copper(II) complexes constructed from salicylic acid and 4,4′-bipyridine

被引：28
|
作者：
Zhu, LG
Kitagawa, S
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Kyoto Univ, Grad Sch Engn, Dept Synth Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期
关键词：
crystal structure; copper complex; salicylic acid; 4,4 '-bipyridine; dimer; network;
D O I：
10.1016/S1387-7003(03)00173-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel complexes, [Cu-2(Hsal)(4)(4,4'-bipyridine)(H2O)(2)(DMF)(2)] (1) (H(2)sal = salicylic acid) and {[Cu(Hsal)(2)(4,4'-bipyridine)](H2O)(H(2)sal)}(n) (2), were synthesized by layered-solution method and structurally characterized. Geometries of copper atoms in both complexes exhibit square pyramidal. Complex 1 is a dimer and hydrogen bonds between water and DMF molecules extend the structure into ID hydrogen bonding network. Complex 2 consists of two-dimensional square framework structure. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：1051 / 1055
页数：5
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