The two-dimensional iron(II)-thiocyanate-4,4′-bipyridine coordination network

被引：29
|
作者：
Adams, Christopher J. [1 ]
Real, Jose Antonio [2 ]
Waddington, Rachel E. [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Valencia, Inst Ciencia Mol, Paterna 46980, Valencia, Spain
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 11期
关键词：
SPIN-CROSSOVER; MAGNETIC-PROPERTIES; FRAMEWORK MATERIAL; CRYSTAL-STRUCTURES; TRANSITION; 2D; 4,4-BIPYRIDINE; COMPLEX; SYSTEMS; EPR;
D O I：
10.1039/c0ce00149j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structures of eight solvates of {Fe(4,4'-bipyridine)(2)(NCS)(2)}(n) have been determined. All of them contain a layered iron-bipyridine-thiocyanate framework formed from approximately square infinite two-dimensional (4,4) iron-bipyridine grids, with the solvent molecules hosted between adjacent layers. All the structures contain the iron(II) centres in the high-spin electronic configuration, and magnetic susceptibility measurements on the toluene and nitrobenzene solvates do not reveal any spin-crossover behaviour.
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收藏
页码：3547 / 3553
页数：7
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