Reactivity of the bis(silyl) palladium(II) complex toward organic isothiocyanates

被引：13
|
作者：
Kim, Yong-Joo [1 ]
Jeon, Hyung-Tak [1 ]
Lee, Kyung-Eun [2 ]
Lee, Soon W. [2 ]
机构：
[1] Kangnung Wonju Natl Univ, Dept Chem, Kangnung 210702, South Korea
[2] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 19-20期
关键词：
Palladium; Dithiocarbonimidato; Diphenylsilanedithiolato; Isothiocyanate; DITHIOCARBONIMIDATO COMPLEXES; DIPALLADIUM COMPLEXES; OXIDATIVE ADDITION; BRIDGING DISILENE; DOUBLE SILYLATION; PLATINUM; LIGANDS; SI; CHEMISTRY; RELEVANT;
D O I：
10.1016/j.jorganchem.2010.06.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The bis(silyl) palladium(II) complex [Pd(SiHPh2)(2)(dmpe)] (dmpe = 1,2-bis(dimethylphosphino) ethane) reacted with organic isothiocyanates ReNCS (R = Ph, Pr-i, allyl) to give a dithiocarbonimidato [Pd(S2C=N-Ph)(dmpe)] (1), a diphenylsilanedithiolato [Pd(S2SiPh2)(dmpe)] (2), or a pi-allyl [(eta(3)-allyl)Pd](NCS) (3) palladium complex, depending on the isothiocyanate type and reaction conditions. In addition, various dithiocarbonimidato Pd(II) complexes were also obtained from trans-[PdEt2L2] (L = PMe3, PMe2Ph) (4-6) or [Pd(styrene)L-2] and organic isothiocyanates. (C) 2010 Elsevier B. V. All rights reserved.
引用
收藏
页码：2258 / 2263
页数：6
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