Reactivity of the bis(silyl) palladium(II) complex toward organic isothiocyanates

被引：13

作者：

Kim, Yong-Joo ^{[1
]}

Jeon, Hyung-Tak ^{[1
]}

Lee, Kyung-Eun ^{[2
]}

Lee, Soon W. ^{[2
]}

机构：

[1] Kangnung Wonju Natl Univ, Dept Chem, Kangnung 210702, South Korea

[2] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 19-20期

关键词：

Palladium; Dithiocarbonimidato; Diphenylsilanedithiolato; Isothiocyanate; DITHIOCARBONIMIDATO COMPLEXES; DIPALLADIUM COMPLEXES; OXIDATIVE ADDITION; BRIDGING DISILENE; DOUBLE SILYLATION; PLATINUM; LIGANDS; SI; CHEMISTRY; RELEVANT;

D O I：

10.1016/j.jorganchem.2010.06.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis(silyl) palladium(II) complex [Pd(SiHPh2)(2)(dmpe)] (dmpe = 1,2-bis(dimethylphosphino) ethane) reacted with organic isothiocyanates ReNCS (R = Ph, Pr-i, allyl) to give a dithiocarbonimidato [Pd(S2C=N-Ph)(dmpe)] (1), a diphenylsilanedithiolato [Pd(S2SiPh2)(dmpe)] (2), or a pi-allyl [(eta(3)-allyl)Pd](NCS) (3) palladium complex, depending on the isothiocyanate type and reaction conditions. In addition, various dithiocarbonimidato Pd(II) complexes were also obtained from trans-[PdEt2L2] (L = PMe3, PMe2Ph) (4-6) or [Pd(styrene)L-2] and organic isothiocyanates. (C) 2010 Elsevier B. V. All rights reserved.

引用

页码：2258 / 2263

页数：6

共 50 条

[1] Reactivities of organic isothiocyanates and thiocyanates toward dialkyl bis(phosphine) complexes of palladium(II) and platinum(II)
Lee, Seon Gye
Choi, Keun-Young
Kim, Yong-Joo
Park, Sujin
Lee, Soon W.
POLYHEDRON, 2015, 85 : 880 - 887
[2] Synthesis, structural characterization and reactivity of a bis(phosphine)(silyl) platinum(II) complex
Li, Yong-Hua
Yang, Cheng-Long
Lai, Wen-Yong
Huang, Zheng-Feng
Wang, Shi
Wang, Lian-Hui
Huang, Wei
JOURNAL OF MOLECULAR STRUCTURE, 2015, 1097 : 181 - 184
[3] Synthesis, structural characterization, and reactivity of a bis (phosphine)(silyl) platinum(II) complex
Zeng, Wen-Jin
Wang, Shi
Mi, Bao-Xiu
Li, Jun-Feng
Lai, Wen-Yong
Li, Yong-Hua
Wang, Lian-Hui
Huang, Wei
JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (23) : 4203 - 4211
[4] Synthesis, Structural Characterization and Reactivity of a Bis(phosphine)(silyl) Platinum(II) Complex
Li, Yonghua
Zeng, Wenjin
Lai, Wenyong
Shimada, Shigeru
Wang, Shi
Wang, Lianhui
Huang, Wei
CHINESE JOURNAL OF CHEMISTRY, 2015, 33 (10) : 1206 - 1210
[5] Synthesis, Structural Studies and Reactivity of Two cis-Bis(phosphine)bis(silyl) Palladium(II) Complexes
Wang, Lizhong
Guo, Jinfei
Li, Yajuan
Su, Yanrong
Liu, Jiawei
Li, Yonghua
Wang, Shi
Shimada, Shigeru
Huang, Wei
CHINESE JOURNAL OF CHEMISTRY, 2017, 35 (04) : 507 - 511
[6] Reactivity of alkynyl Pd(II) azido complexes toward organic isocyanides, isothiocyanates, and nitriles
Kim, YJ
Lee, SH
Lee, SH
Jeon, SI
Lim, MS
Lee, SW
INORGANICA CHIMICA ACTA, 2005, 358 (03) : 650 - 658
[7] Dinuclear palladium-azido complexes containing thiophene derivatives: reactivity toward organic isocyanides and isothiocyanates
Chang, Xiaohong
Kim, Mi-Young
Kim, Yong-Joo
Huhc, Hyun Sue
Lee, Soon W.
DALTON TRANSACTIONS, 2007, (07) : 792 - 801
[8] Reactivity of di(azido)bis(phosphine) complexes of Ni(II), Pd(II) and Pt(II) toward organic isothiocyanates: synthesis, structures, and properties of bis(tetrazole-thiolato) and bis(isothiocyanato) complexes
Kim, YJ
Han, JT
Kang, S
Han, WS
Lee, SW
DALTON TRANSACTIONS, 2003, (17) : 3357 - 3364
[9] Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex
Sun, Shuang-Shuang
Guo, Jin-Fei
Wang, Shi
Huang, Chao
Zhu, Jia-Yi
Li, Yong-Hua
Huang, Wei
INORGANICA CHIMICA ACTA, 2016, 451 : 157 - 161
[10] SYNTHESES AND INTERCONVERSION OF [BIS(SILYL)ALKENE]PALLADIUM(0) AND BIS(SILYL)PALLADIUM(II) COMPLEXES - A MECHANISTIC MODEL FOR PALLADIUM-CATALYZED BIS-SILYLATION
MURAKAMI, M
YOSHIDA, T
ITO, Y
ORGANOMETALLICS, 1994, 13 (07) : 2900 - 2902

← 1 2 3 4 5 →