Energy transfer from Ce3+ to Dy3+ ions for white light emission in Sr2MgAl22O36:Ce3+, Dy3+ phosphor

被引:17
|
作者
Dev, Kapil [1 ]
Selot, Anupam [1 ]
Nair, Govind B. [2 ]
Barai, Vijay L. [2 ]
Haque, Fozia Z. [3 ]
Aynyas, M. [4 ]
Dhoble, S. J. [2 ]
机构
[1] Sadhu Vaswani Coll, Dept Phys, Bhopal 462030, India
[2] RTM Nagpur Univ, Dept Phys, Nagpur 440033, Maharashtra, India
[3] Maulana Azad Natl Inst Technol, Dept Phys, Opt Nanomat Lab, Bhopal 462003, India
[4] Govt PG Coll, Dept Phys, Sehore 462016, India
关键词
Photoluminescence; Energy transfer; Phosphor; Aluminate; PHOTOLUMINESCENCE PROPERTIES; LUMINESCENCE PROPERTIES; NANO PHOSPHOR; COLOR; EU2+; PR3+;
D O I
10.1016/j.jlumin.2018.10.092
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Series of Sr2MgAl22O36:Ce3+, Sr2MgAl22O36:Dy3+ and Sr2MgAl22O36:Ce3+,Dy3+ phosphors were synthesized by urea-assisted combustion method. The identification of phase and morphology of the prepared samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Photoluminescence excitation (PLE) and emission spectra of the as-prepared samples were investigated. Photoluminescence studies revealed that the luminescence intensity of Ce3+ ion increases with increasing concentration in Sr2MgAl22O36:Ce3+ and no concentration quenching have been witnessed. Similar trend was observed for Sr2MgAl22O36:Dy3+ with increasing Dy3+ concentration. The energy transfer from Ce3+ to Dy3+ in Sr2MgAl22O36 host has been achieved successfully to produce white light emission. The calculated Commission Internationale de L'Eclairage (CIE) chromaticity coordinates for the Sr2MgAl22O36:Ce3+, Dy3+ phosphor are (x = 0.302, y = 0.357). The values of CIE chromaticity coordinates and correlated color temperature (CCT) of 6798 K endorse Sr2MgAl22O36:Ce3+, Dy3+ phosphor as potential candidate for cool white-light emission.
引用
收藏
页码:380 / 385
页数:6
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