Nanoconfined ionic liquids: effect of surface charges on flow and molecular layering

被引:106
|
作者
Bou-Malham, Ibrahim [1 ]
Bureau, Lionel [1 ]
机构
[1] Univ Paris 06, CNRS, UMR7588, Inst Nanosci Paris, F-75015 Paris, France
关键词
ROOM-TEMPERATURE; FRICTION; FILMS;
D O I
10.1039/c0sm00377h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ionic liquids have remarkable physico-chemical properties that make them highly attractive as new solvents or electrolytes in applications ranging from solar cells to MEMS lubrication, in which their flow properties in the vicinity of solid surfaces are crucial. We have performed a study of the nanorheology of two ionic liquids confined in molecularly thin films which shows how surface charges drastically affect their molecular structure and flow properties.
引用
收藏
页码:4062 / 4065
页数:4
相关论文
共 50 条
  • [41] I&EC 43-Interfacial layering in ionic liquids
    Ocko, Benjamin M.
    Mezger, M.
    Reichert, H.
    Sloutskin, E.
    Schroeder, H.
    Deutsch, M.
    Dosch, H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
  • [42] Effect of Surface Force on Nanoconfined Shale-Gas Flow in Slit Channels
    Gao, Yanling
    Wu, Keliu
    Chen, Zhangxin
    Li, Jing
    Li, Qian
    Dong, Xiaohu
    Tian, Weibing
    Liu, Yishan
    Zhu, Qingyuan
    Bi, Jianfei
    SPE JOURNAL, 2021, 26 (01): : 448 - 460
  • [43] Effect of surface bilayer charges on the magnetic field around ionic channels
    Gomes Soares, Marilia Amavel
    Cortez, Celia Martins
    de Oliveira Cruz, Frederico Alan
    Silva, Dilson
    PHYSICA B-CONDENSED MATTER, 2017, 504 : 86 - 91
  • [44] Surface layering in ionic liquids: An X-ray reflectivity study (vol 127, pg 7796, 2005)
    Sloutskin, E
    Ocko, BM
    Tamam, L
    Kuzmenko, I
    Gog, T
    Deutsch, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) : 18333 - 18333
  • [45] Molecular Mechanisms Underlying Lubrication by Ionic Liquids: Activated Slip and Flow
    Han, Mengwei
    Espinosa-Marzal, Rosa M.
    LUBRICANTS, 2018, 6 (03):
  • [46] Ionic liquids start to flow
    Scott, Alex
    Chemical Week, 2002, 164 (35)
  • [47] Molecular dynamics simulation of ionic liquids:: The effect of electronic polarizability
    Yan, TY
    Burnham, CJ
    Del Pópolo, MG
    Voth, GA
    JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (32): : 11877 - 11881
  • [48] Molecular solvent effect on the acidity constant of protic ionic liquids
    Adam, Claudia
    Bravo, M. Virginia
    Mancini, Pedro M. E.
    TETRAHEDRON LETTERS, 2014, 55 (01) : 148 - 150
  • [49] Stability and decay of surface electrostatic charges in liquids
    Li, Zhaoyang
    Long, Yu
    Zhong, Junwen
    NANO ENERGY, 2021, 81
  • [50] Solvation in molecular ionic liquids
    Shim, Y
    Duan, JS
    Choi, MY
    Kim, HJ
    JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (13): : 6411 - 6414