Catalytic carbonylation of glycerin by urea in the presence of zinc mesoporous system for the synthesis of glycerol carbonate

被引：0
|
作者：
Yoo, JW
Mouloungui, Z
机构：
来源：
NANOTECHNOLOGY IN MESOSTRUCTURED MATERIALS | 2003年 / 146卷
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The glycerin is transformed into glycerol carbonate by reaction with urea in the presence of a series of heterogeneous catalyst system including metallic sulfates or zinc organomettallic sulfate. Zinc sulfate exhibits characteristic catalytic behaviour in the carbonylation of glycerin into glycerol carbonate wich gives a good molar yield of 86% at 140degreesC, 30 mbar for 2 hours.
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页码：757 / 760
页数：4
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