A convenient epoxidation of alpha,beta-unsaturated ketones with sodium hypochlorite under phase transfer conditions catalysed by hexaethlguanidinium chloride (HEGCI)

被引：0

作者：

Schlama, T ^{[1
]}

Alcaraz, L ^{[1
]}

Mioskowski, C ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,CNRS,CHIM BIOORGAN LAB,FAC PHARM,F-67401 ILLKIRCH GRAFFENS,FRANCE

来源：

SYNLETT | 1996年 / 06期

关键词：

alpha; beta-epoxycarbonyls; alpha'; alpha'-dichloro-alpha beta-epoxycyclohexanones; sodium hypochlorite; guanidinium salts; phase transfer epoxidation;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

For the first time hexaethylguanidinium chloride (HEGCl) was used as an efficient phase transfer agent in the epoxidation of alpha,beta-unsaturated ketones under biphasic conditions.

引用

页码：571 / &

页数：3

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