Tributylammonium chlorochromate, (C4H9)3NH[CrO3Cl] (TriBACC):: A new, mild and stable oxidant for organic substrates

被引：13

作者：

Ghammamy, S ^{[1
]}

Mazareey, M ^{[1
]}

机构：

[1] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin, Iran

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2005年 / 70卷 / 05期

关键词：

oxidant; chromium(VI) reagent; tributylammonium chlorochromate; oxidation; organic substrates;

D O I：

10.2298/JSC0505687G

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild and stable new chromium(VI) reagent from tributylamine is described. Orange crystalline tributylammonium chlorochromate(VI), (C4H9)(3)NE[CrO3Cl], (TriBACC), is easily prepared in a nearly quantitative yield by the interaction of tributylamine with CrO3 and hydrochloric acid in a 1:2:2 mole ratio. This reagent is a versatile reagent for the effective and selective oxidation of organic substratcs, in particular for alcohols, under mild conditions.

引用

页码：687 / 693

页数：7

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