Tributylammonium chlorochromate, (C4H9)3NH[CrO3Cl] (TriBACC):: A new, mild and stable oxidant for organic substrates

被引：13
|
作者：
Ghammamy, S [1 ]
Mazareey, M [1 ]
机构：
[1] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin, Iran
来源：
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2005年 / 70卷 / 05期
关键词：
oxidant; chromium(VI) reagent; tributylammonium chlorochromate; oxidation; organic substrates;
D O I：
10.2298/JSC0505687G
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mild and stable new chromium(VI) reagent from tributylamine is described. Orange crystalline tributylammonium chlorochromate(VI), (C4H9)(3)NE[CrO3Cl], (TriBACC), is easily prepared in a nearly quantitative yield by the interaction of tributylamine with CrO3 and hydrochloric acid in a 1:2:2 mole ratio. This reagent is a versatile reagent for the effective and selective oxidation of organic substratcs, in particular for alcohols, under mild conditions.
引用
收藏
页码：687 / 693
页数：7
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