Silver nanoparticles as an efficient, heterogeneous and recyclable catalyst for synthesis of β-enaminones

被引:60
|
作者
Bhatte, Kushal D. [1 ]
Tambade, Pawan J. [1 ]
Dhake, Kishor P. [1 ]
Bhanage, Bhalchandra M. [1 ]
机构
[1] Inst Chem Technol Autonomous, Dept Chem, Bombay 400019, Maharashtra, India
关键词
Silver nanoparticles; beta-Enaminones; beta-Enamino esters; Heterogeneous; Recyclable catalyst; STEREOSELECTIVE-SYNTHESIS; GREEN SYNTHESIS; ALDEHYDE; CHLORIDE; ALKYNE; CORE;
D O I
10.1016/j.catcom.2010.06.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple and efficient protocol has been developed for synthesis of beta-enaminones and beta-enamino esters catalyzed by silver nanoparticles as a novel, heterogeneous, moisture stable and recyclable catalyst under mild reaction conditions. The reaction was optimized with respect to various parameters such as catalyst screening, catalyst loading, different solvents and temperature. The silver nanoparticle exhibited excellent activity and the methodology is applicable to diverse substrates providing good to excellent yields of desired products. The catalyst was recycled for three consecutive cycles without any significant loss in activity. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1233 / 1237
页数:5
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