Low-cost instant CO generation at room temperature using formic acid, mesyl chloride and triethylamine

被引：31

作者：

Veryser, Cedrick ^{[1
]}

Van Mileghem, Seger ^{[1
]}

Egle, Brecht ^{[1
]}

Gilles, Philippe ^{[1
]}

De Borggraeve, Wim M. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem Mol Design & Synth, Celestijnenlaan 200F,Box 2404, B-3001 Leuven, Belgium

来源：

REACTION CHEMISTRY & ENGINEERING | 2016年 / 1卷 / 02期

基金：

比利时弗兰德研究基金会;

关键词：

PALLADIUM-CATALYZED CARBONYLATION; EX-SITU GENERATION; CARBON-MONOXIDE; ARYL HALIDES; N-FORMYLSACCHARIN; AMINOCARBONYLATIONS; PRESSURE; FORMATES;

D O I：

10.1039/c6re00006a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three low-cost standard lab chemicals, formic acid, mesyl chloride and triethylamine, were used for instant carbon monoxide (CO) generation at room temperature. Subsequently this gas was implemented in palladium-catalysed aminocarbonylation chemistry. Moreover, C-13-enriched formic acid was used as one of the most economical CO precursors for C-13-carbonyl labelling.

引用

页码：142 / 146

页数：5

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