Low-cost instant CO generation at room temperature using formic acid, mesyl chloride and triethylamine

被引：31

作者：

Veryser, Cedrick ^{[1
]}

Van Mileghem, Seger ^{[1
]}

Egle, Brecht ^{[1
]}

Gilles, Philippe ^{[1
]}

De Borggraeve, Wim M. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem Mol Design & Synth, Celestijnenlaan 200F,Box 2404, B-3001 Leuven, Belgium

来源：

REACTION CHEMISTRY & ENGINEERING | 2016年 / 1卷 / 02期

基金：

比利时弗兰德研究基金会;

关键词：

PALLADIUM-CATALYZED CARBONYLATION; EX-SITU GENERATION; CARBON-MONOXIDE; ARYL HALIDES; N-FORMYLSACCHARIN; AMINOCARBONYLATIONS; PRESSURE; FORMATES;

D O I：

10.1039/c6re00006a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three low-cost standard lab chemicals, formic acid, mesyl chloride and triethylamine, were used for instant carbon monoxide (CO) generation at room temperature. Subsequently this gas was implemented in palladium-catalysed aminocarbonylation chemistry. Moreover, C-13-enriched formic acid was used as one of the most economical CO precursors for C-13-carbonyl labelling.

引用

页码：142 / 146

页数：5

共 50 条

[1] Hydrogen generation from formic acid decomposition at room temperature using a NiAuPd alloy nanocatalyst
Wang, Zhi-Li
Ping, Yun
Yan, Jun-Min
Wang, Hong-Li
Jiang, Qing
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (10) : 4850 - 4856
[2] Miniaturized quadrature coupler using low-cost instant inkjet printing technology
Babale, S. A.
Rahim, S. K. A.
MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, 2017, 59 (08) : 1819 - 1824
[3] Insights into hydrogen generation from formic acid on PtRuBiOx in aqueous solution at room temperature
Hu, Chaoquan
Ting, Siu-Wa
Chan, Kwong-Yu
Huang, Wei
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (21) : 8720 - 8731
[4] Synthesis of nanoporous PdAg nanoalloy for hydrogen generation from formic acid at room temperature
Mandal, Kaustab
Bhattacharjee, Debaleena
Dasgupta, Subrata
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (14) : 4786 - 4793
[5] An Efficient CoAuPd/C Catalyst for Hydrogen Generation from Formic Acid at Room Temperature
Wang, Zhi-Li
Yan, Jun-Min
Ping, Yun
Wang, Hong-Li
Zheng, Wei-Tao
Jiang, Qing
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (16) : 4406 - 4409
[6] Different low-cost materials to prevent the alteration induced by formic acid on unstable glasses
Arevalo, Rodrigo
Mosa, Jadra
Aparicio, Mario
Palomar, Teresa
HERITAGE SCIENCE, 2021, 9 (01)
[7] Different low-cost materials to prevent the alteration induced by formic acid on unstable glasses
Rodrigo Arévalo
Jadra Mosa
Mario Aparicio
Teresa Palomar
Heritage Science, 9
[8] Growth of Co-doped ZnO thin films exhibiting room temperature ferromagnetism using a low-cost spray pyrolysis technique
Vikas Thakur
Urvashi Verma
Bulletin of Materials Science, 2022, 45
[9] Growth of Co-doped ZnO thin films exhibiting room temperature ferromagnetism using a low-cost spray pyrolysis technique
Thakur, Vikas
Verma, Urvashi
BULLETIN OF MATERIALS SCIENCE, 2022, 45 (01)
[10] Promoting Selective Generation of Formic Acid from CO2 Using Mn(bpy)(CO)3Br as Electrocatalyst and Triethylamine/Isopropanol as Additives
Madsen, Monica R.
Ronne, Magnus H.
Heuschen, Marvin
Golo, Dusanka
Ahlquist, Marten S. G.
Skrydstrup, Troels
Pedersen, Steen U.
Daasbjerg, Kim
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (48) : 20491 - 20500

← 1 2 3 4 5 →