Polymer-supported synthesis of mono-substituted porphyrins

被引：7
|
作者：
Yang, QF [1 ]
Streb, KK [1 ]
Borhan, B [1 ]
机构：
[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 39期
关键词：
porphyrins; soluble polymers; cross-linked polymers; mono-substituted tetraarylporphyrins;
D O I：
10.1016/j.tetlet.2005.07.131
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Anchoring of substituted benzaldehydes to soluble and insoluble polymers allows for the synthesis of mono-substituted tetraarylporphyrins without the production of di-, tri-, and tetra-substituted porphyrin side products. The exclusion of the aforementioned side products during the synthesis of mono-substituted tetraarylporphyrin acids greatly reduced the complexity during purification of the product. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6737 / 6740
页数：4
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