MODELING OF THE MECHANISM FOR THE ACIDOLYSIS OF EPICHLOROHYDRIN BY ALIPHATIC AND AROMATIC CARBOXYLIC ACIDS CATALYZED BY AMINES

被引：6
|
作者：
Sinel'nikova, M. A. [1 ]
Shved, E. N. [1 ]
Usachev, V. V. [1 ]
Oleinik, N. M. [1 ]
机构：
[1] Donetsk Natl Univ, UA-83055 Donetsk, Ukraine
来源：
THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2010年 / 46卷 / 03期
关键词：
-oxide; carboxylic acids; catalysis; mathematical modeling;
D O I：
10.1007/s11237-010-9135-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A model was constructed for the mechanism of the reaction of aliphatic and aromatic carboxylic acids with epichlorohydrin catalyzed by tertiary amines. A mechanism for the catalysis of the transfer of the anion of the nucleophilic reagent by an ion pair was proposed taking account of the kinetic data and selected chemical and mathematical models.
引用
收藏
页码：168 / 175
页数：8
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