Crystal structure of the orthorhombic modification of [Bi(HEdta)]•2H2O

被引：0
|
作者：
Davidovich, RL
Ilyukhin, AB
Hu, SZ
机构：
[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
[2] NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
[3] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
来源：
CRYSTALLOGRAPHY REPORTS | 1998年 / 43卷 / 04期
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D O I：
暂无
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of alpha-[Bi(HEdta]. 2H(2)O is studied by X-ray diffraction (R = 0.058) to elucidate the stereochemical behaviour of the lone electron pair in this compound. The coordination number of bismuth is 8, The polyhedron has an irregular shape. The O(4) atom of the protonated acetate arm is included in Bi coordination. A stereochemical activity of the lone electric pair determines the difference in the Bi-O bond lengths.
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页码：605 / 607
页数：3
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