One-pot synthesis of nickel oxide-carbon composite microspheres on nickel foam for supercapacitors

被引:24
|
作者
Wang, Yan [1 ]
Xing, Shuangxi [2 ]
Zhang, Enrui [3 ]
Wei, Jiatong [1 ,3 ]
Suo, Hui [3 ]
Zhao, Chun [3 ]
Zhao, Xu [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China
[2] NE Normal Univ, Inst Colloid & Interface Chem, Fac Chem, Changchun 130024, Peoples R China
[3] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
ELECTROCHEMICAL CAPACITORS; EVOLUTION REACTION; ELECTRODE MATERIAL; NANOFIBERS; CATALYST; SPHERES; FILMS; MNO2; NIO;
D O I
10.1007/s10853-011-6021-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Using glucose and Ni(NO(3))(2) as precursors, the nickel oxide-carbon (NiO-C) composites are directly formed on the nickel foam by a one-pot hydrothermal method. The product presents a spherical morphology with the carbon component in the composite being a non-graphitic phase. The presence of NiO provides additional pseudo-capacitance for the electrode materials and the composites exhibit superior specific capacitance to the pure carbon materials formed on the nickel foam. Apart from that, compared with the nickel sheet substrate, the utilization of the nickel foam benefits for the achievement of higher performance and stability owing to its unique 3D structure. The highest specific capacitance for the NiO-C-nickel foam electrode of 265.3 F g(-1) is obtained at a discharge current density of 0.25 A g(-1).
引用
收藏
页码:2182 / 2187
页数:6
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