Click chemistry as an efficient tool to access β-cyclodextrin dimers

被引:45
|
作者
Mourer, Maxime [1 ]
Hapiot, Frederic [1 ]
Monflier, Eric [1 ]
Menuel, Stephane [1 ]
机构
[1] Univ Artois, Fac Jean Perrin, CNRS, Unite Catalyse & Chim Solide,UMR 8181, F-62307 Lens, France
关键词
click chemistry; cycloaddition; cyclodextrin; dimers; supramolecular chemistry;
D O I
10.1016/j.tet.2008.05.095
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Cu(I)-catalyzed azide-alkyne cycloaddition has enabled practical and efficient preparation of hydroxylated, permethylated and peracylated beta-cyclodextrin dimers in good yields starting from mono-6-azido-beta-cyclodextrin and ortho-, meta- or para-bis-(prop-2-ynyloxy)benzenes as spacers. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7159 / 7163
页数:5
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