Research on the preparation of metallocene/Hβ catalyst for n-hexane isomerization

被引:0
|
作者
Chen, Jin-She [1 ]
Song, Zhao-Yang [1 ]
Duan, Zun-Bin [1 ]
Zhu, Li-Jun [1 ]
Xia, Dao-Hong [1 ]
机构
[1] China Univ Petr, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China
关键词
N-hexane Isomerization; Metallocene Catalysts; Reaction Conditions;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The research on isomerization technology of n-alkanes is necessary, and there is few study on metallocene catalysts for isomerization of n-alkanes. In this study, novel ferrocene/H beta, acetylferrocene/H beta and titanocene dichloride/H beta catalysts for isomerization of n-hexane was prepared, and the isomerization activity of them was investigated. Moreover, the optimum reaction conditions for catalysts were investigated, respectively. The results showed that the optimal loading of active components were 0.2%, 0.2% and 2.0%, and the optimal reaction temperature of them was 300 and 310 degrees C, respectively. The study of this kind of catalysts has importantly theoretical and practical significance.
引用
收藏
页码:277 / 282
页数:6
相关论文
共 50 条
  • [41] COKE POISONING EFFECT ON XYLENE ISOMERIZATION AND ON N-HEXANE CRACKING OVER H-OFFRETITE
    GUISNET, M
    BOURDILLON, G
    GUEGUEN, C
    ZEOLITES, 1984, 4 (04): : 308 - 309
  • [42] Simultaneous desulphurization, isomerization and benzene saturation of n-hexane fraction on Pt-H/MOR
    Hancsók, J
    Magyar, S
    Nguyen, KVS
    Szoboszlai, Z
    Kalló, D
    Holló, A
    Szauer, G
    MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B, 2005, 158 : 1717 - 1724
  • [43] KINETICS OF N-HEXANE ISOMERIZATION ON H-MORDENITE CONTAINING 0.5-PERCENT-PT
    NAGY, E
    FETTING, F
    CHEMIE INGENIEUR TECHNIK, 1981, 53 (09) : 729 - 731
  • [44] HYDROISOMERIZATION OF N-HEXANE ON MORDENITE SHELL-CATALYST
    GUBICZA, L
    UJHIDY, A
    EXNER, H
    CATALYSIS TODAY, VOL 5, NO 2: PROCEEDINGS OF THE IVTH BELGIAN-HUNGARIAN CONFERENCE ON CATALYSIS, 1989, : 139 - 148
  • [45] Hydro-isomerization of n-Hexane on Bi-functional Catalyst: Effect of Total and Hydrogen Partial Pressures
    Dao Thi Kim Thoa
    Luu Cam Loc
    INTERNATIONAL CONFERENCE ON CHEMICAL ENGINEERING, FOOD AND BIOTECHNOLOGY (ICCFB2017), 2017, 1878
  • [46] Kinetics of the low-temperature isomerization of n-hexane on the NIP-3A catalyst in an isothermal flow reactor
    A. S. Kinyakin
    E. A. Glushachenkova
    P. N. Borutskii
    A. S. Shuvalov
    Yu. A. Pisarenko
    Theoretical Foundations of Chemical Engineering, 2008, 42 : 815 - 821
  • [47] Effect of carriers on physico-chemical properties and activity of Pd nano-catalyst in n-hexane isomerization
    Cam Loc Luu
    Thi Kim Thoa Dao
    Tri Nguyen
    Thanh Huong Bui
    Thi Ngoc Yen Dang
    Minh Nam Hoang
    Si Thoang Ho
    ADVANCES IN NATURAL SCIENCES-NANOSCIENCE AND NANOTECHNOLOGY, 2013, 4 (04)
  • [48] Kinetics of the low-temperature isomerization of n-hexane on the NIP-3A catalyst in an isothermal flow reactor
    Kinyakin, A. S.
    Glushachenkova, E. A.
    Borutskii, P. N.
    Shuvalov, A. S.
    Pisarenko, Yu. A.
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2008, 42 (06) : 815 - 821
  • [49] Mechanism for isomerization of n-hexane over sulfated zirconia: role of hydrogen
    Duchet, JC
    Guillaume, D
    Monnier, A
    van Gestel, J
    Szabo, G
    Nascimento, P
    Decker, S
    CHEMICAL COMMUNICATIONS, 1999, (18) : 1819 - 1820
  • [50] A Novel B-Doped NiP/Hβ Catalyst for n-hexane Isomerization with Synergistic Catalytic Mechanism of Metal Sites-Acid Sites
    Li, Zihan
    Yang, Lingbin
    Zhu, Lijun
    Xia, Daohong
    CATALYSIS LETTERS, 2022, 152 (06) : 1844 - 1853