Hydrogenation of CO2-Expanded Liquid Terpenes: Phase Equilibrium-Controlled Kinetics

被引：0
|
作者：
Bogel-Lukasik, Ewa [1 ]
Serbanovic, Ana
Bogel-Lukasik, Rafal [1 ]
Banet-Osuna, Anna
Najdanovic-Visak, Vesna [1 ]
da Ponte, Manuel Nunes [1 ]
机构：
[1] FCT Univ Nova Lisboa, Dept Quim, REQUIMTE, P-2829516 Caparica, Portugal
来源：
GAS-EXPANDED LIQUIDS AND NEAR-CRITICAL MEDIA: GREEN CHEMISTRY AND ENGINEERING | 2009年 / 1006卷
关键词：
SUPERCRITICAL CARBON-DIOXIDE; SELECTIVE HYDROGENATION; ALPHA-PINENE; PRESSURE; LIMONENE; BEHAVIOR; CO2; COMPLEXES; LINALOOL; SOLVENTS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogenation of two liquid terpenes, alpha-pinene and limonene, was carried out in the presence of high-pressure carbon dioxide, using carbon-supported Pt catalysts. Phase equilibrium data on terpene + CO2 + hydrogen were used to interpret the kinetics of hydrogenation in liquid + vapor systems close to the critical lines of the mixtures.
引用
收藏
页码：191 / 201
页数：11
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