A palaeomagnetic study of the Ronda peridotites (southern Spain) has been carried out on 301 samples from 20 sites, spread along the three main outcrops of the ultrabasic complex: Ronda, Ojen and Carratraca massifs. Different lithologies and outcrops with different degrees of serpentinization have been sampled and analysed. Rock magnetic experiments have been carried out on a representative set of samples. These measurements include: Curie curves, hysteresis cycles, isothermal remanent magnetization (IRM) acquisition curves, thermal demagnetization of IRM imparted along three orthogonal axes and magnetic bulk susceptibility. Results indicate that magnetite is the main magnetic mineral present in the samples. Stepwise thermal and alternating field (AF) demagnetization of the natural remanent magnetization (NRM) reveals the presence of a characteristic remanent magnetization (ChRM) carried by magnetite, and in some sepentinized samples, a northward component with variable unblocking temperatures up to 250-575 degreesC. The appearance and the relative intensity of this northward component are strongly related to serpentinization degree. Taking into account the geological history of the peridotites, the ChRM has been considered as a thermo-chemical remanent magnetization acquired during the first serpentinization phase associated to the post-metamorphic cooling of this unit: On the basis of radiometric and fission track analysis, the ChRM is proposed to have been acquired between 20 and 17-18 Ma. The inclination of the mean direction of the ChRM statistically coincides with the expected inclination for stable Iberia during the Oligocene-Miocene. The declination of the ChRM differs from the expected declination, indicating clockwise block rotations of 41 +/- 12degrees about vertical axes since the cooling of the peridotites. When applying a compositional layering correction, the ChRM directions fail to pass this kind of fold test, thus, the compositional layering was not a palaeohorizontal during ChRM acquisition time. Normal and reversed polarities of the ChRM are reported, showing that at least one reversal of the Earth's magnetic field took place during ChRM acquisition process. A tentative polarity zonation within the peridotitic outcrops is also suggested. No evidence is found from these data for the previously proposed simultaneity between post-metamorphic cooling and rotation of the peridotites. (C) 2003 Elsevier B.V. All rights reserved.