Aqua(3,5-dimethylpyrazole)(N-salicylideneglycinato)copper(II)

被引：22
|
作者：
Warda, SA
Friebel, C
Sivy, J
Plesch, G
Svajlenova, O
机构：
[1] COMENIUS UNIV BRATISLAVA,FAC PHARM,DEPT ANALYT CHEM,BRATISLAVA 83232,SLOVAKIA
[2] FAC NAT SCI,DEPT INORGAN CHEM,BRATISLAVA 84215,SLOVAKIA
[3] COMENIUS UNIV BRATISLAVA,FAC PHARM,DEPT CHEM THEORY DRUGS,BRATISLAVA 83232,SLOVAKIA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270196008578
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aqua(3,5-dimethylpyrazole-N-1)(N-salicylideneglycinato-O,N, O')copper(II), [CU(C9H7NO3)(C5H8N2)(H2O)], adopts a square-pyramidal Cu-II coordination with the tridentate N-salicylideneglycinato Schiff base dianion and the 3,5-dimethylpyrazole ligand bound in the basal plane. The water molecule occupies the apical site. The complex molecules are arranged in four magnetically non-equivalent orientations, two at a time forming zigzag chains. Both the interchain Cu...Cu spacing of 7.396 Angstrom and the intrachain Cu...Cu distance of 6.880 Angstrom are too large for effective dipolar coupling between the paramagnetic Cu-II centres, in agreement with the results of electron paramagnetic resonance (EPR) spectroscopy.
引用
收藏
页码：2763 / 2766
页数：4
相关论文
共 50 条
  • [31] ON THE REACTION OF 3,5-DIMETHYLPYRAZOLE WITH ACETYLENIC ESTERS
    ELGUERO, J
    DELAHOZ, A
    PARDO, C
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (03): : 427 - 431
  • [32] 1-(hydroxymethyl)-3,5-dimethylpyrazole
    Evans, IR
    Szécsényi, KM
    Leovac, VM
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O625 - O626
  • [33] Copper(II) and Zinc(II) Complexes with Heterocyclic Acid Anions and 3,5-Dimethylpyrazole: Synthesis, Structure, and Biological Properties
    M. A. Uvarova
    M. V. Novikova
    V. A. Eliseenkova
    D. E. Baravikov
    F. M. Dolgushin
    O. B. Bekker
    E. V. Fatushina
    M. A. Kiskin
    I. L. Eremenko
    I. A. Lutsenko
    Russian Journal of Coordination Chemistry, 2023, 49 : 680 - 687
  • [34] Copper(II) and Zinc(II) Complexes with Heterocyclic Acid Anions and 3,5-Dimethylpyrazole: Synthesis, Structure, and Biological Properties
    Uvarova, M. A.
    Novikova, M. V.
    Eliseenkova, V. A.
    Baravikov, D. E.
    Dolgushin, F. M.
    Bekker, O. B.
    Fatushina, E. V.
    Kiskin, M. A.
    Eremenko, I. L.
    Lutsenko, I. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (10) : 680 - 687
  • [35] PLATINUM(II) AND PALLADIUM(II) COMPLEXES WITH 3,5-DIMETHYLPYRAZOLE CARBAMIDE-1
    SAFRONOVA, LA
    SHEBALDOVA, AD
    KOORDINATSIONNAYA KHIMIYA, 1989, 15 (10): : 1380 - 1382
  • [36] [N,N-bis(3,5-dimethylpyrazol-1-yl-methyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole)copper(II) diperchlorate
    Boyd, PDW
    Burrell, AK
    Rickard, CEF
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1549 - 1551
  • [37] Synthesis, characterisation, and copper(II)-assisted P-N bond cleavage of bis(3,5-dimethylpyrazolyl)chlorophosphine oxide and isolation and characterisation of 3,5-dimethylpyrazole complexes of copper(II)
    Bhattachajee, M
    Datta, R
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1997, 36 (07): : 593 - 595
  • [38] SULFONAMIDES .5. SULFONAMIDE DERIVATIVES OF 1-(CHLOROPHENYL)-3,5-DIMETHYLPYRAZOLE AND 1-(DICHLOROPHENYL)-3,5-DIMETHYLPYRAZOLE
    WRZECIONO, U
    ACTA POLONIAE PHARMACEUTICA, 1975, 32 (06): : 645 - 650
  • [39] Aqua(pyridine-κN)(N-salicylideneglycinato-κ3N,O,O′)copper(II)
    Li, YG
    Zhu, HL
    Chen, XZ
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2385 - M2387
  • [40] Solvent induced reactivity of 3,5-dimethylpyrazole towards zinc (II) carboxylates
    Sarma, Rupam
    Kalita, Dipjyoti
    Baruah, Jubaraj B.
    DALTON TRANSACTIONS, 2009, (36) : 7428 - 7436
12345