{N,N'-[2,2'-(Ethane-1,2-diyldisulfanediyl)di-o-phenylene]bis(quinoline-2-carboxamidato)}copper(II)

被引：0
|
作者：
Meghdadi, Soraia [1 ]
Mirkhani, Valiollah [1 ]
Ford, Peter C. [2 ]
机构：
[1] Univ Isfahan, Dept Chem, Esfahan 8174673441, Iran
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金：
美国国家科学基金会;
关键词：
COORDINATION CHEMISTRY; COPPER(II) COMPLEXES; HEXADENTATE LIGANDS; CRYSTAL-STRUCTURE; REACTIVITY;
D O I：
10.1107/S1600536811019581
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(C(34)H(24)N(4)O(2)S(2))] or [Cu(bqdapte)], where H(2)bqdapte is 1,2-{bis[2-(quinoline-2-carboxamido)phenyl]sulfanyl}ethane, the CuII ion is coordinated to the dianionic hexadentate bqdapte2- ligand by two amide and two quinoline N atoms and two thioether S atoms. In the observed conformation of the hexadentate ligand, the quinoline rings attain positions related by a twofold axis. The Cu atom displays a Jahn-Teller-distorted octahedral CuN(4)S(2) geometry axially compressed along the two trans-configured Cu-N(amidate) bonds.
引用
收藏
页码：M820 / U1662
页数：11
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