New synthesis of triphenylbismuth diaroxides

被引：2
|
作者：
Sharutin, VV [1 ]
Egorova, IV
Tsiplukhina, TV
Molokov, AA
Fukin, GK
机构：
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk, Russia
[2] Razuvaev Inst Organomet Chem, Nizhnii Novgorod, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2005年 / 75卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
Hydrogen; Ether; Hydrogen Peroxide; Crystal Structure; Phenol;
D O I：
10.1007/s11176-005-0338-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of triphenylbismuth, hydrogen peroxide, and phenol (molar ratio I : 1:2) in ether was used to synthesize triphenylbismuth diaroxides Ph3Bi(OAr)(2) [Ar = C6H3(NO2)(2)-2,4, C6H2(NO2)(3)-2,4,6, C6H3Cl2-2,6, C6H2Cl3-2,4,6, C6H3Br2-2,4, C6H2Br3-2,4,6, C6H2Br2-2,4,Me-6, C6H2Br2-2,6, No-2-4]. At an equimolar reagent ratio, bridged bismuth compounds (Ph3BiOAr)(2)O are formed. The crystal structure of bis(2,4-dinitrophenoxy)triphenylbismuth Ph3Bi[OC6H3(NO2)(2)-2,4](2) was studied by X-ray diffraction to show that the bismuth atom has a distorted trigonal bipyramidal coordination and the 2,4-dinitrophenoxyl ligands are axial. The CBiC and OBiO angles are 109.6(5)degrees, 122.3(5)degrees, 128.1(5)degrees, and 175.6(3)degrees. The Bi-O-1,O-6 and Bi-C bond lengths are 2.256(10), 2.242(9) and 2.18(1), 2.18(1), 2.19(1) angstrom, respectively.
引用
收藏
页码：873 / 875
页数：3
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