Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations

被引：77
|
作者：
Ackermann, Lutz [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2010年 / 50卷 / 5-6期
关键词：
arylation; C-H bond activation; cross-coupling; palladium; preligands; PALLADIUM-PHOSPHINOUS ACID; BIPHENYLENE-SUBSTITUTED RUTHENOCENYLPHOSPHINE; SUZUKI-MIYAURA; GRIGNARD-REAGENTS; F ACTIVATION; ARYL CHLORIDES; COORDINATION CHEMISTRY; EFFICIENT SYNTHESIS; ALKENYL HALIDES; C-3; ARYLATION;
D O I：
10.1002/ijch.201000043
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Progress in the use of heteroatom-substituted secondary phosphine oxides (HASPO) as bifunctional preligands in transition-metal-catalyzed cross-coupling reactions as well as C-H bond functionalizations with challenging substrates is summarized herein until July 2010.
引用
收藏
页码：652 / 663
页数：12
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