Chiral [(dialkylamino)methyl](phospholyl)ferrocene ligands as a new class of 1,2-disubstituted ferrocene ligands

被引：30

作者：

Mourgues, S ^{[1
]}

Serra, D ^{[1
]}

Lamy, F ^{[1
]}

Vincendeau, S ^{[1
]}

Daran, JC ^{[1
]}

Manoury, E ^{[1
]}

Gouygou, M ^{[1
]}

机构：

[1] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 15期

关键词：

ferrocenes; phospholes; N; P ligands; asymmetric catalysis;

D O I：

10.1002/ejic.200200671

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An efficient synthesis of new chiral [(dialkylamino)methyl]-(phospholyl)ferrocenes in an enantiomerically pure form has been developed. These new chiral N,P ligands have been tested in the palladium-catalyzed allylic substitution reaction. High activities and moderate enantioselectivities (up to 67% ee) were observed. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

引用

页码：2820 / 2826

页数：7

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