Ligand-Free Ag(I)-Catalyzed Carboxylation of Terminal Alkynes with CO2

被引：173
|
作者：
Zhang, Xiao [1 ]
Zhang, Wen-Zhen [1 ]
Ren, Xiang [1 ]
Zhang, Lin-Lin [1 ]
Lu, Xiao-Bing [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 09期
基金：
中国国家自然科学基金;
关键词：
CATALYZED DIRECT CARBOXYLATION; CARBON-DIOXIDE INCORPORATION; N-HETEROCYCLIC CARBENES; ONE-POT SYNTHESIS; C-H BONDS; STEREOSELECTIVE-SYNTHESIS; SONOGASHIRA REACTION; PALLADIUM; ACIDS; DERIVATIVES;
D O I：
10.1021/ol200638z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient approach to selectively prepare a wide range of functionalized propiolic acids was developed by Agl-catalyzed carboxylation of terminal alkynes using carbon dioxide as carboxylative agent under ligand-free conditions.
引用
下载
收藏
页码：2402 / 2405
页数：4
相关论文
共 50 条
  • [21] DBU and copper(I) mediated carboxylation of terminal alkynes using supercritical CO2 as a reactant and solvent
    Li, Fa-Wang
    Suo, Quan-Ling
    Hong, Hai-Long
    Zhu, Ning
    Wang, Ya-Qi
    Han, Li-Min
    TETRAHEDRON LETTERS, 2014, 55 (29) : 3878 - 3880
  • [22] Response to Commentary by T. Mita on Transition Metal-Catalyzed Carboxylation of Terminal Alkynes with CO2
    He, Liang-Nian
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2019, 16 (05) : 409 - 409
  • [23] DFT Studies on the Silver-Catalyzed Carboxylation of Terminal Alkynes with CO2: An Insight into the Catalytically Active Species
    Liu, Chuang
    Luo, Yi
    Zhang, Wenzheng
    Qu, Jingping
    Lu, Xiaobing
    ORGANOMETALLICS, 2014, 33 (12) : 2984 - 2989
  • [24] A Study on C-H Carboxylation Reaction of Terminal Alkynes with CO2 in Supercritical CO2
    Li, Fawang
    Suo, Quanling
    Hong, Hailong
    Zhu, Ning
    Wang, Yaqi
    Han, Limin
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2014, 34 (10) : 2172 - 2177
  • [25] Gold(I)-Organic Frameworks as Catalysts for Carboxylation of Alkynes with CO2
    Wei, Rong-Jia
    Xie, Mo
    Xia, Ri-Qin
    Chen, Jun
    Hu, Hua-Juan
    Ning, Guo-Hong
    Li, Dan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (41) : 22720 - 22727
  • [26] Cu(I)-Catalyzed Carboxylative Coupling of Terminal Alkynes, Allylic Chlorides, and CO2
    Zhang, Wen-Zhen
    Li, Wen-Jie
    Zhang, Xiao
    Zhou, Hui
    Lu, Xiao-Bing
    ORGANIC LETTERS, 2010, 12 (21) : 4748 - 4751
  • [27] Iron-Catalyzed Ligand-Free Three-Component Coupling Reactions of Aldehydes, Terminal Alkynes, and Amines
    Li, Pinhua
    Zhang, Yicheng
    Wang, Lei
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (09) : 2045 - 2049
  • [28] Ligand-Free Silver Nanoparticles for CO2 Electrocatalytic Reduction to CO
    Mattarozzi, Francesco
    Visser, Nienke
    de Rijk, Jan Willem
    Ngene, Peter
    de Jongh, Petra
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 2022 (29)
  • [29] Ligand-free copper-catalyzed regio- and stereoselective 1,1-alkylmonofluoroalkylation of terminal alkynes
    Lv, Yunhe
    Pu, Weiya
    Wang, Xiaoxing
    CHEMICAL COMMUNICATIONS, 2020, 56 (85) : 12933 - 12936
  • [30] Silver(I)-catalyzed carboxylation of arylboronic esters with CO2
    Zhang, Xiao
    Zhang, Wen-Zhen
    Shi, Ling-Long
    Guo, Chun-Xiao
    Zhang, Ling-Ling
    Lu, Xiao-Bing
    CHEMICAL COMMUNICATIONS, 2012, 48 (50) : 6292 - 6294
12345