Ligand-Free Ag(I)-Catalyzed Carboxylation of Terminal Alkynes with CO2

被引：174
|
作者：
Zhang, Xiao [1 ]
Zhang, Wen-Zhen [1 ]
Ren, Xiang [1 ]
Zhang, Lin-Lin [1 ]
Lu, Xiao-Bing [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 09期
基金：
中国国家自然科学基金;
关键词：
CATALYZED DIRECT CARBOXYLATION; CARBON-DIOXIDE INCORPORATION; N-HETEROCYCLIC CARBENES; ONE-POT SYNTHESIS; C-H BONDS; STEREOSELECTIVE-SYNTHESIS; SONOGASHIRA REACTION; PALLADIUM; ACIDS; DERIVATIVES;
D O I：
10.1021/ol200638z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient approach to selectively prepare a wide range of functionalized propiolic acids was developed by Agl-catalyzed carboxylation of terminal alkynes using carbon dioxide as carboxylative agent under ligand-free conditions.
引用
收藏
页码：2402 / 2405
页数：4
相关论文
共 50 条
  • [1] Ligand-free Ag(I)-catalyzed carboxylative coupling of terminal alkynes, chloride compounds, and CO2
    Zhang, Xiao
    Zhang, Wen-Zhen
    Shi, Ling-Long
    Zhu, Chuang
    Jiang, Jiao-Lai
    Lu, Xiao-Bing
    [J]. TETRAHEDRON, 2012, 68 (44) : 9085 - 9089
  • [2] Ligand-free copper catalyzed hydrazination of terminal alkynes
    Peltier, Jesse
    Jazzar, Rodolphe
    Melaimi, Mohand-Ameziane
    Bertrand, Guy
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [3] Transition Metal-Catalyzed Carboxylation of Terminal Alkynes with CO2
    Qiao, Chang
    Cao, Yu
    He, Liang-Nian
    [J]. MINI-REVIEWS IN ORGANIC CHEMISTRY, 2018, 15 (04) : 283 - 290
  • [4] Copper(I)@Carbon-Catalyzed Carboxylation of Terminal Alkynes with CO2 at Atmospheric Pressure
    Yu, Bing
    Xie, Jia-Ning
    Zhong, Chun-Lai
    Li, Wei
    He, Liang-Nian
    [J]. ACS CATALYSIS, 2015, 5 (07): : 3940 - 3944
  • [5] Efficient Carboxylation of Terminal Alkynes with Carbon Dioxide Catalyzed by Ligand-Free Copper Catalyst under Ambient Conditions
    Wang, Wan-Hui
    Jia, Lihong
    Feng, Xiujuan
    Fang, Dingqiao
    Guo, Hongyu
    Bao, Ming
    [J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 8 (08) : 1501 - 1505
  • [6] Research advances on the carboxylation of terminal alkynes with CO2
    Li M.
    Zhang L.
    Zhang A.
    Zhao Y.
    Sun N.
    Wei W.
    [J]. Huagong Jinzhan/Chemical Industry and Engineering Progress, 2021, 40 (06): : 3421 - 3433
  • [7] Carboxylation of terminal alkynes with CO2 over Ag loaded ZIF-8
    Sun, Nannan
    Shi, Jialin
    Zhang, Lina
    Shen, Qun
    Gao, Qiang
    Wei, Wei
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [8] Ligand-free copper(I)-catalyzed Sonogashira-type coupling of arylboronic acids with terminal alkynes
    Pan, Changduo
    Luo, Fang
    Wang, Wenhui
    Ye, Zhishi
    Cheng, Jiang
    [J]. TETRAHEDRON LETTERS, 2009, 50 (35) : 5044 - 5046
  • [9] Ligand-free MnBr2-Catalyzed Chemo- and Stereoselective Hydroboration of Terminal Alkynes
    Pawar, Rameshwar B.
    Karmur, Mital H.
    Punji, Benudhar
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2024, 19 (09)
  • [10] C?H Carboxylation of Terminal Alkynes Catalyzed by Low Loadings of Silver(I)/DMSO at Ambient CO2 Pressure
    Arndt, Matthias
    Risto, Eugen
    Krause, Thilo
    Goossen, Lukas J.
    [J]. CHEMCATCHEM, 2012, 4 (04) : 484 - 487
12345