General and Selective Palladium-Catalyzed Oxidative Esterification of Alcohols

被引：225
|
作者：
Gowrisankar, Saravanan [1 ]
Neumann, Helfried [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leiden Inst Katalyse eV, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 22期
关键词：
alcohols; aldehydes; esters; oxidative esterification; palladium; PD-II-HYDROPEROXIDE; AEROBIC OXIDATION; MOLECULAR-OXYGEN; BORROWING HYDROGEN; AMIDE SYNTHESIS; HETEROARYL BROMIDES; EFFICIENT CATALYST; KINETIC RESOLUTION; ARYL CHLORIDES; METHYL-ESTERS;
D O I：
10.1002/anie.201008035
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Selectively esterified: Primary alcohols react with dioxygen as a benign oxidant in a palladium-catalyzed oxidative esterification (see scheme). The corresponding aldehydes and esters are formed highly selectively depending on the catalyst system. The reactions take place in the presence of commercially available ligands without the need for additional organic hydrogen acceptors. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：5139 / 5143
页数：5
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