Catalysis with Doped Sol-Gel Silicates

被引：34

作者：

Ciriminna, Rosaria ^{[1
]}

Cara, Piera Demma ^{[2
]}

Sciortino, Marzia ^{[2
]}

Pagliaro, Mario ^{[1
]}

机构：

[1] CNR, Ist Studio Mat Nanostrutturati, I-90146 Palermo, PA, Italy

[2] Univ Palermo, Dipartimento Ingn & Tecnol Agro Forestali, I-90128 Palermo, Italy

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 05期

关键词：

fine chemistry; heterogeneous catalysis; organically modified silica (ORMOSIL); sol-gel chemistry; xerogels; RECYCLABLE CATALYSTS; OXIDATION; TEMPO; PERFORMANCE; PERRUTHENATE; COMPLEXES; PALLADIUM; ALCOHOLS; RHODIUM; GREEN;

D O I：

10.1002/adsc.201000731

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Silicates doped with catalytic species have only been slowly adopted by the fine chemicals and pharmaceutical industries, in spite of their remarkable and unique properties such as pronounced physical and chemical stability; high (enantio)selective activity and ease of materials production and application. This is now changing thanks to stricter safety regulations and to concomitant success of the first commercial catalysts. In this account we tell the story of these materials and identify some deficiencies in the innovation process that may serve as lesson in guiding the future management of innovation in these relevant industries.

引用

页码：677 / 687

页数：11

共 50 条

[31] Erbium photoluminescence response related to nanoscale heterogeneities in sol-gel silicates
Vasconcelos, H. C.
Meirelles, M. G.
Rivera-Lopez, F.
JOURNAL OF RARE EARTHS, 2013, 31 (01) : 18 - 26
[32] Sol-gel glass from organic modified silicates for optics applications
Rizzo, G
Barilà, P
Galvagno, S
Neri, G
Arena, A
Patanè, S
Saitta, G
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) : 1017 - 1021
[33] Activation of protease by sol-gel entrapment into organically modified hybrid silicates
Furukawa, S
Ono, T
Ijima, H
Kawakami, K
BIOTECHNOLOGY LETTERS, 2002, 24 (01) : 13 - 16
[34] APROTIC METHODOLOGY FOR CONSTRUCTING MULTICOMPONENT SILICATES - AN ALTERNATIVE TO SOL-GEL SYNTHESIS
FEHER, FJ
WELLER, KJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 174 - INOR
[35] Excitation energy dependence of luminescent sol-gel organically modified silicates
Sá Ferreira, R.A.
Carlos, L.D.
De Zea Bermudez, V.
Thin Solid Films, 1999, 343 : 476 - 480
[36] Structural investigations and luminescence properties of nanocrystalline europium-doped yttrium silicates prepared by a sol-gel technique
Cannas, Carla
Mainas, Marina
Musinu, Anna
Piccaluga, Giorgio
Enzo, Stefano
Bazzoni, Marco
Speghini, Adolfo
Bettinelli, Marco
OPTICAL MATERIALS, 2007, 29 (06) : 585 - 592
[37] Quantum yields of sol-gel glasses and PMMA/sol-gel composites doped with quinine sulphate.
MenesesNava, MA
ChavezCerda, S
SanchezMondragon, JJ
17TH CONGRESS OF THE INTERNATIONAL COMMISSION FOR OPTICS: OPTICS FOR SCIENCE AND NEW TECHNOLOGY, PTS 1 AND 2, 1996, 2778 : 395 - 396
[38] Synthesis of nanocrystalline gadolinium doped ceria via sol-gel combustion and sol-gel synthesis routes
Zarkov, Aleksej
Stanulis, Andrius
Salkus, Tomas
Kezionis, Algimantas
Jasulaitiene, Vitalija
Ramanauskas, Rimantas
Tautkus, Stasys
Kareiva, Aivaras
CERAMICS INTERNATIONAL, 2016, 42 (03) : 3972 - 3988
[39] Recent advances in sol-gel catalysis for fine chemicals production
Pagliaro, Mario
Ciriminna, Rosaria
Palmisano, Giovanni
Sciortino, Marzia
Beland, Francois
Pandarus, Valerica
Tremblay, Lynda
CHIMICA OGGI-CHEMISTRY TODAY, 2009, 27 (03): : 13 - 16
[40] Dynamic catalysis in aerobic oxidation by sol-gel living materials
Ciriminna, R
Campestrini, S
Carraro, M
Pagliaro, M
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (05) : 846 - 850

← 1 2 3 4 5 →